Enantioselective hydrogenations with highly mesoporous carbon supported Pd catalysts

Graphic Highly mesoporous carbon supported Pd catalysts were prepared using sodium formate and hydrogen for the reduction of the catalyst precursors. These catalysts were tested in the enantioselective hydrogenation of isophorone and of 2-benzylidene-1-benzosuberone. The support and the catalysts we...

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Bibliographic Details
Published in:Journal of molecular catalysis. A, Chemical Chemical, 2004-04, Vol.212 (1), p.245-250
Main Authors: Sı́pos, É, Fogassy, G, Tungler, A, Samant, P.V, Figueiredo, J.L
Format: Article
Language:English
Subjects:
2-Benzyl-1-benzosuberone
Catalysis
Catalytic reactions
Chemistry
Chiral modifier
Colloidal state and disperse state
Enantioselective hydrogenation
Exact sciences and technology
General and physical chemistry
Isophorone
Mesoporous carbon
Porous materials
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:Graphic Highly mesoporous carbon supported Pd catalysts were prepared using sodium formate and hydrogen for the reduction of the catalyst precursors. These catalysts were tested in the enantioselective hydrogenation of isophorone and of 2-benzylidene-1-benzosuberone. The support and the catalysts were characterized by different methods such as nitrogen adsorption, hydrogen chemisorption, SEM, XPS, and TPD.
ISSN:1381-1169
1873-314X
DOI:10.1016/j.molcata.2003.10.044