Photolysis and photocatalysis of methylene blue by ferrite bismuth nanoparticles under sunlight irradiation

• Published in: Journal of molecular catalysis. A, Chemical Chemical, 2013-10, Vol.377, p.197-203
• Main Authors: Soltani, Tayyebe, Entezari, Mohammad H.
• Format: Article
• Language: English
• Subjects: BiFeO3; Catalysis; Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; Methylene blue; Photochemistry; Photodegradation; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Sunlight irradiation; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Ultrasound
• ISSN: 1381-1169; 1873-314X
• DOI: 10.1016/j.molcata.2013.05.004

•The BFO synthesized via ultrasound showed a high adsorption and complete degradation of MB under sunlight at low pH.•The reduction of COD to 83% proved the mineralization of the MB.•MB exhibited different behaviors at different pH under direct sunlight irradiation.•In basic medium, MB degraded by only photolysis under sunlight irradiation.•MB degraded on BFO by a pseudo first-order kinetic model. Ferrite bismuth nanoparticles as a visible light photocatalyst were successfully synthesized via ultrasound. The optimum conditions were found and applied for the sono-synthesis of the catalyst. The product was characterized by different methods. The nanoparticles were used for the degradation of methylene blue as a typical dye pollutant. In acidic medium, the photocatalytic degradation was carried out under direct sunlight irradiation. In basic medium, without catalyst, the methylene blue was degraded through photolysis under sunlight irradiation. The effect of parameters such as the amount of catalyst and initial concentration of the dye was investigated on the removal efficiency of methylene blue. The adsorption isotherm and the kinetic of photocatalytic degradation were studied under different conditions. Furthermore, the degradation efficiency and the chemical oxygen demand reduction were 100% and 83% for the photocatalytic process, respectively.