Photocatalytic activity of magnetically recoverable MnFe2O4/g-C3N4/TiO2 nanocomposite under simulated solar light irradiation

• Published in: Journal of molecular catalysis. A, Chemical Chemical, 2014-12, Vol.395, p.373-383
• Main Authors: Vignesh, K., Suganthi, A., Min, Bong-Ki, Kang, Misook
• Format: Article
• Language: English
• Subjects: Catalysis; Chemistry; Exact sciences and technology; General and physical chemistry; Methyl orange; Nanocomposite; Photocatalysis; Photochemistry; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Solar light; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; TiO2
• ISSN: 1381-1169; 1873-314X
• DOI: 10.1016/j.molcata.2014.08.040

UV–vis absorption changes of MO (10ppm) in the presence of MnFe2O4/g-C3N4/TiO2 (0.5g/L) under simulated solar light irradiation. •A magnetic nanocomposite was prepared by chemical impregnation method.•The absorption of TiO2 was red shifted after modification with MnFe2O4/g-C3N4.•99.27% of MO degradation was achieved using MnFe2O4/g-C3N4/TiO2.•MnFe2O4/g-C3N4/TiO2 could be easily recovered from water using a magnet. A magnetic nanocomposite composed of manganese ferrite (MnFe2O4), graphitic-carbon nitride (g-C3N4) and titanium dioxide-P25 (TiO2) was synthesized via chemical impregnation method. The as-synthesized nanocomposite (MnFe2O4/g-C3N4/TiO2) was characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), high resolution TEM (HR-TEM) elemental mapping, energy dispersive X-ray spectroscopy (EDX), UV–visible diffuse reflectance spectroscopy (UV-vis-DRS), photoluminescence (PL), B.E.T. surface area analysis, X-ray photo-electron spectroscopy and vibrating sample magnetometery (VSM) techniques. The band gap of TiO2 was decreased after surface modification with MnFe2O4/g-C3N4. The photocatalytic activity was tested for the degradation of methyl orange (MO) dye as a model pollutant under simulated solar light irradiation. It was found that MnFe2O4/g-C3N4/TiO2 displayed excellent photocatalytic activity than that of g-C3N4, MnFe2O4 and MnFe2O4/g-C3N4. The enhancement in the photocatalytic activity was ascribed to the synergism between TiO2, g-C3N4 and MnFe2O4. VSM results revealed that ferromagnetism was retained in the nanocomposite (MnFe2O4/g-C3N4/TiO2) and it could be easily removed using an external magnet after the photo-reaction. Besides, the durability and stability of magnetic nanocomposite was tested by recycling experiments.