Nanoparticles silica anchored Cu(II) and V(IV) scorpionate complexes for selective catalysis of cyclohexane oxidation

• Published in: Journal of molecular catalysis. A, Chemical Chemical, 2015-05, Vol.400, p.139-146
• Main Authors: Machado, Kelly, Mukhopadhyay, Suman, Mishra, Gopal S.
• Format: Article
• Language: English
• Subjects: Cyclohexane; Mechanism; Nano-catalyst; Oxygen; Scorpionate compounds; Selectivity
• ISSN: 1381-1169; 1873-314X
• DOI: 10.1016/j.molcata.2015.01.026

[Display omitted] •Functionalized nanoperticles SiNPs support preparation.•Immobilized tri(pyrazolyl) ethanol Cu and V-complexes as supported catalyst.•Nano-catalysts test in gas–liquid phase O2 oxidation of cyclohexane.•High catalytic TONs and selective product. Silica nanoparticles (SiNPs) with the average size of 8.4nm have been synthesized and functionalized with the reaction of Cl-sulfonylphenylethyl tri-methoxysilane. These functionalized SiNPs have been anchored in scorpionate compounds i.e., [CuCl2{HOCH2C(pz)3}], [VOCl2{HOCH2C(pz)3}], and [V(acac) {HOCH2C(pz)3}] as hybrid nano-catalysts. The presence of metal compound over support was confirmed with FTIR, EPR, TGA, TEM, XRD, AAS, and TEM–EDS. These catalysts have produced remarkable high TONs ca. 1216–2607 with yields 13.7–27.3% for the selective oxidation of cyclohexane (Cy-hx) with molecular oxygen under relatively mild conditions. Very high about 95% products selectivity of Cy=O and Cy-OH was also attained. The TGA analysis indicates that all the catalysts were thermally stable under operating reaction temperature and reusable up to five more cycles.