Apparent molar volumes of divalent transition metal bromides in dimethyl sulfoxide solutions

Densities and apparent molar volumes for dimethyl sulfoxide solutions of manganese(II), cobalt(II), nickel(II), copper(II) and zinc(II) bromides are reported. The differences in the apparent molar volumes of the salts are discussed and interpreted in terms of bromo-complex formation. An influence of...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular liquids 2005-01, Vol.116 (2), p.61-65
Main Authors: Warmińska, Dorota, Krakowiak, Joanna, Grzybkowski, Wacław
Format: Article
Language:English
Subjects:
Apparent molar volumes
Bromides
Complex formation
Dimethyl sulfoxide
DMSO solutions
Partial molar volumes
Transition metal cations
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Densities and apparent molar volumes for dimethyl sulfoxide solutions of manganese(II), cobalt(II), nickel(II), copper(II) and zinc(II) bromides are reported. The differences in the apparent molar volumes of the salts are discussed and interpreted in terms of bromo-complex formation. An influence of the nature and structure of the metal ion on the coordination state of the salt in solution is discussed.
ISSN:0167-7322
1873-3166
DOI:10.1016/j.molliq.2004.07.077