Selective oxidation of alcohol to carbonyl compound catalyzed by l-aspartic acid coupled imidazolium based ionic liquid

A clean and highly efficient alcohol oxidation, using hydrogen peroxide in the presence of l-aspartic acid coupled imidazolium based ionic liquid [L-AAIL], was achieved under solvent free condition with excellent yield. In this catalytic system, variety of alcohol including inactive aliphatic alcoho...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular liquids 2012-09, Vol.173, p.180-183
Main Authors: Karthikeyan, Parasuraman, Arunrao, Aswar Sachin, Narayan, Muskawar Prashant, Kumar, Sythana Suresh, Kumar, S. Senthil, Bhagat, Pundlik Rambhau
Format: Article
Language:English
Subjects:
Alcohol
Aldehyde
Green oxidation
Hydrogen peroxide
Ionic liquid
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A clean and highly efficient alcohol oxidation, using hydrogen peroxide in the presence of l-aspartic acid coupled imidazolium based ionic liquid [L-AAIL], was achieved under solvent free condition with excellent yield. In this catalytic system, variety of alcohol including inactive aliphatic alcohol, could be completely oxidized with high conversion and selectivity. The catalyst can be recycled and reused for seven runs without any significant loss of its activity. [Display omitted] ► An efficient [L-AAIL] catalyst for oxidation reaction. ► The procedure is easy and does not require special precautions. ► The catalyst was reused for several runs without loss of its catalytic activity.
ISSN:0167-7322
1873-3166
DOI:10.1016/j.molliq.2012.06.018