Effect of the hockey-shaped mesogen as an additive on the critical behaviour at the smectic A to nematic phase transition

• Published in: Journal of molecular liquids 2016-07, Vol.219, p.608-613
• Main Authors: Chakraborty, Susanta, Chakraborty, Anish, Das, Malay Kumar, Weissflog, Wolfgang
• Format: Article
• Language: English
• Subjects: Critical exponent; Hockey stick-shaped mesogen; Optical birefringence; Phase transition; Pretransitional fluctuation
• ISSN: 0167-7322; 1873-3166
• DOI: 10.1016/j.molliq.2016.04.002

We present systematic experimental data on high resolution measurements of temperature dependence of optical birefringence (Δn) in a binary liquid crystalline system comprising calamitic 4-cyano-4′-octyloxybiphenyl (8OCB) and a hockey stick-shaped compound, 4-(3-decyloxyphenyliminomethyl) phenyl 4-decyloxycinnamate (SF7). The hockey stick-shaped mesogen shows a smectic A (SmA) phase in addition to two polymorphic tilted smectic phases. From an analysis of the Δn data, a quotient Q(T) has been derived which exhibits power law divergences both above and below the smectic A-nematic (SmA-N) phase transition. A noticeable shrinkage in width of the nematic range has been observed for a small increase in concentration of the angular mesogenic dopant. In the vicinity of the SmA-N phase transition, the values of effective critical exponent (α′), characterizing the critical fluctuation at this transition, have appeared to be in between those predicted by the 3D-XY and tricritical hypothesis. Furthermore, with increasing hockey stick-shaped molecular concentration, the SmA-N transition shows a tendency to be driven towards a first order nature. •High resolution birefringence measurements have been performed on binary mixtures of a hockey stick-shaped LC and 8OCB.•Increasing hockey stick-shaped molecule concentration leads to a considerable decrease in the nematic width.•The enhancing S-Ψ coupling drives the SmA-N transition towards first order nature.•The molecular bend in the guest mesogen has found to play an important role in deciding the resultant phase-character.