Casein as a natural protein to inhibit the corrosion of mild steel in HCl solution

• Published in: Journal of molecular liquids 2019-02, Vol.276, p.694-704
• Main Authors: Rabizadeh, Taher, Asl, Shahin Khameneh
• Format: Article
• Language: English
• Subjects: Adsorption; AFM; Corrosion; EIS; Green inhibitor; Mild steel
• ISSN: 0167-7322; 1873-3166
• DOI: 10.1016/j.molliq.2018.11.162

In this research, the effects of casein on the corrosion behavior of mild steel in 0.1 M HCl were investigated by different analytical techniques. According to weight loss measurements, an increase in the concentration of casein from 50 ppm to 400 ppm resulted in a decrease in the corrosion rate of mild steel, for example, from 34.3 mpy to 3.9 mpy as compared to 98.1 mpy calculated for the casein-free solution at 298 K. However, increasing the temperature from 298 K to 343 K had adverse effects on the surface coverage, and the corrosion inhibition efficiency of casein. Based on thermodynamic calculations, in the presence of 400 ppm casein the corrosion activation energy and the enthalpy of activation increased from 8.61 kJ·mol−1 to 45.89 kJ·mol−1 and from 5.95 kJ·mol−1 to 43.23 kJ·mol−1, respectively. Potentiodynamic polarization experiments revealed a considerable decrease in the corrosion current density when casein was dissolved in the corrosive solution. This is in accordance with the observed increase in the charge transfer resistance from 121.4 Ω·cm2 to 917.9 Ω·cm2 measured by EIS. ATR-FTIR and EDS analyses confirmed the surface adsorption of casein on mild steel. AFM also illustrated an improvement in the surface properties of the samples in the presence of casein. [Display omitted] •The presence of casein significantly reduces the corrosion of mild steel in 0.1 M HCl solution.•The corrosion inhibition efficiency of casein depends on its concentration.•In the presence of casein, an increase in charge transfer resistance was recorded by EIS.•The ATR-FTIR and EDS analyses confirmed the surface adsorption of casein.•Casein inhibits the corrosion of mild steel via both electrostatic and charge sharing interactions.