A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki–Miyaura cross-coupling reactions

trans-[PdBr 2(NHC)Im] was prepared by reacting the corresponding imidazolium (Im) salt with palladium(II) acetate in dimethylsulfoxide in an in-situ reaction without generating a free carbene. Both the salt and the complex were characterized spectroscopically and by X-ray structure analysis. The com...

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Bibliographic Details
Published in:Journal of molecular structure 2008-11, Vol.890 (1), p.192-197
Main Authors: Linninger, Claudia S., Herdtweck, Eberhardt, Hoffmann, Stephan D., Herrmann, Wolfgang A., Kühn, Fritz E.
Format: Article
Language:English
Subjects:
Imidazolium salt
N-heterocyclic carbene
Palladium
Suzuki–Miyaura cross-coupling
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Summary:trans-[PdBr 2(NHC)Im] was prepared by reacting the corresponding imidazolium (Im) salt with palladium(II) acetate in dimethylsulfoxide in an in-situ reaction without generating a free carbene. Both the salt and the complex were characterized spectroscopically and by X-ray structure analysis. The complex was tested in homogeneous Suzuki–Miyaura cross-coupling reactions.
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2008.05.037