The structural studies of the 4-nitrophenyl[bis(benzylthio)]methane by X-ray and spectroscopic methods. The possible outcome in its proton donor properties

4-Nitrophenyl[bis(benzylthio)]methane was synthesized and used in structural study by X-ray diffraction combined with NMR and spectrophotometric method. In the crystal structure the molecule assumes the conformation where the acidic H-atom is difficult to access due to sterical hindrances of three s...

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Bibliographic Details
Published in:Journal of molecular structure 2009-06, Vol.928 (1), p.54-58
Main Authors: Binkowska, Iwona, Ratajczak–Sitarz, Małgorzata, Katrusiak, Andrzej, Jarczewski, Arnold
Format: Article
Language:English
Subjects:
4-Nitrophenyl[bis(benzylsulfonyl)]methane
4-Nitrophenyl[bis(benzylthio)]methane
Carbon acid
Crystal structure
X-Ray diffraction
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Summary:4-Nitrophenyl[bis(benzylthio)]methane was synthesized and used in structural study by X-ray diffraction combined with NMR and spectrophotometric method. In the crystal structure the molecule assumes the conformation where the acidic H-atom is difficult to access due to sterical hindrances of three surrounding phenyls. The acidic properties of 4-nitrophenyl[bis(benzylthio)]methane have been compared and discussed with the analogous disulfonyl carbon acid 4-nitrophenyl[bis(benzylsulfonyl)]methane.
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2009.03.013