Spectroscopic, luminescence, electrochemical and antimicrobial studies of lanthanide complexes of bis-benzimidazole derived ligands

► The complexes [Ln(L1)2Cl3H2O] and [Ln(L2)2Cl3H2O]·2H2O were prepared and characterized. ► TGA data suggested presence of the coordinated and the lattice water molecules. ► The covalency parameters (β, b1/2 and δ) have been evaluated from the electronic spectral data. ► CV studies indicate formatio...

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Bibliographic Details
Published in:Journal of molecular structure 2013-04, Vol.1037, p.402-411
Main Authors: Siddiqi, Zafar A., Shahid, Anjuli M., Khalid, Mohd, Sharma, Prashant K., Siddique, Armeen
Format: Article
Language:English
Subjects:
Antimicrobial activities
antimicrobial properties
bacteria
Covalency parameters
Dipodal tridentate ligand
electrochemistry
ethane
fungi
Lanthanide salts
luminescence
nuclear magnetic resonance spectroscopy
spectral analysis
TGA
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Summary:► The complexes [Ln(L1)2Cl3H2O] and [Ln(L2)2Cl3H2O]·2H2O were prepared and characterized. ► TGA data suggested presence of the coordinated and the lattice water molecules. ► The covalency parameters (β, b1/2 and δ) have been evaluated from the electronic spectral data. ► CV studies indicate formation of stable quasi-reversible redox couples in solution. ► The antimicrobial activities of the complexes have also been evaluated. The lanthanide complexes of [1,2-bis(benzimidazole-2-yl)ethane dihydrochloride], L1·2HCl and [1,4-bis(benzimidazole-2-onium)butane dihydrochloride], L2·2HCl having molecular formulae [Ln(L1)2Cl3H2O] and [Ln(L2)2Cl3H2O]·2H2O (Ln=La3+, Pr3+, Nd3+ and Gd3+), respectively, were prepared and characterized through IR, 1H and 13C NMR, ESI-mass, UV–visible and luminescence spectroscopic techniques. TGA data suggested presence of the coordinated and the lattice water. The oscillator strengths of the f–f transitions and the covalency parameters (β, b1/2 and δ) have been evaluated from the electronic spectral data. The proposed octa coordinate geometry for the complexes has been ascertained from the molecular model computations. CV studies indicate formation of stable quasi-reversible redox couples PrIII/IV, Nd III/IV and GdIII/IV in solution. The in vitro antimicrobial activities of the complexes have been evaluated against gram +ve and gram −ve bacteria and fungi.
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2012.12.062