Synthesis, characterization and X-ray crystal structure of a mononuclear ampyrone based zinc complex

•Synthesis of zinc complex derived from an antipyrene derivative.•Single crystal structure.•Spectroscopic studies.•Hirshfeld surface studies. A novel mononuclear zinc complex derived from a pyrazole-based ligand was studied. The structure of the complex was explored using C, H, N, FT-IR, NMR, and UV...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular structure 2022-07, Vol.1259, p.132727, Article 132727
Main Authors: Azam, Mohammad, Al-Resayes, Saud I., Trzesowska-Kruszynska, Agata, Kruszynski, Rafal
Format: Article
Language:English
Subjects:
Ampyrone
Hirshfeld surface analysis
Single crystal
TGA
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:•Synthesis of zinc complex derived from an antipyrene derivative.•Single crystal structure.•Spectroscopic studies.•Hirshfeld surface studies. A novel mononuclear zinc complex derived from a pyrazole-based ligand was studied. The structure of the complex was explored using C, H, N, FT-IR, NMR, and UV/Vis studies, thermogravimetric analysis, and single-crystal X-ray crystallography. The single XRD study shows the coordination of the zinc ion to the alkoxide oxygen atom, two chloride ions, and one additional oxygen atom from the ethanol molecule in the complex. The intermolecular interactions in the complex were investigated using Hirshfeld surface analysis and revealed that the H…H is the most important interaction, accounting for 45.9% of the overall crystal packing contribution of the complex.
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2022.132727