Influence of the 8-quinolinol concentration and solution pH on the interfacial properties of self-healing hydrotalcite coating applied to AZ31 magnesium alloy

• Published in: Materials today communications 2021-03, Vol.26, p.101923, Article 101923
• Main Authors: Anjum, Muhammad Junaid, Zhao, Jingmao, Tabish, Mohammad, Murtaza, Hassan, Asl, Vahdat Zahedi, Yang, Qiuxiang, Malik, Muhammad Uzair, Ali, Hamid, Yasin, Ghulam, Khan, Waheed Qamar
• Format: Article
• Language: English
• Subjects: 8-quinolinol; Autonomous self-healing; Corrosion protection; Hydrophobic coating; Hydrotalcite coating; Inhibitor
• ISSN: 2352-4928; 2352-4928
• DOI: 10.1016/j.mtcomm.2020.101923

[Display omitted] The hydrotalcite-like (HT) coatings can provide an enhanced interfacial barrier to protect Mg alloys from corrosion. Therefore, 8-quinolinol (8Q), a green corrosion inhibitor, was intercalated in MgAl-based HT with varying concentration and pH values. The results revealed that the corrosion resistance was significantly improved when the pH of the solution was maintained at 10 with a 0.30 M concentration of 8Q. The hydrophobicity was also introduced to MgAl HT with the intercalation of 8Q, which was retained even after the long immersion. Furthermore, the self-healing performance of 8Q-intercalated HT was confirmed by single-frequency electrochemical impedance spectroscopy (EIS), which is a suitable method for in-situ evaluation of self-healing herein reported for the first time to evaluate the HT coatings. This thorough investigation of the hydrophobic MgAl HT coating is meaningfully supportive for researchers and engineers to have a deep understanding of its possibility for real-world applications in the area of corrosion and prevention.