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High peroxidase-like activity achieved by the synergistic effect in Ag-Cu-CuFe2O4

Nanozymes as peroxidase-like artificial enzymes have been widely used in different fields. However, the low activity of nanozyme resulted in a high concentration of the substrate used. Paramagnetic Ag-Cu-CuFe2O4 was firstly synthesized by a one-step solvothermal method, where Ag+ was facilely reduce...

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Bibliographic Details
Published in:Materials today communications 2022-12, Vol.33, p.104544, Article 104544
Main Authors: Xia, Fan, Nan, Zhaodong
Format: Article
Language:English
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Summary:Nanozymes as peroxidase-like artificial enzymes have been widely used in different fields. However, the low activity of nanozyme resulted in a high concentration of the substrate used. Paramagnetic Ag-Cu-CuFe2O4 was firstly synthesized by a one-step solvothermal method, where Ag+ was facilely reduced to Ag0 by the solvent (ethylene glycol). The Ag/Cu molar ratio was 0.05. Ag-Cu-CuFe2O4 showed higher peroxidase-like activity than that of Cu-CuFe2O4. Ag0 in the nanozyme enhanced the redox capacity and accelerated the charge transfer rate. Ag-Cu-CuFe2O4 was used to detect H2O2 with the limit of detection (LOD) as small as 0.37 μM, which is lower than similar nanozymes. [Display omitted]
ISSN:2352-4928
2352-4928
DOI:10.1016/j.mtcomm.2022.104544