Effects of H2S content on the corrosion behavior of gas storage reservoir injection and production pipeline steel in CO2-H2S environment

• Published in: Materials today communications 2024-12, Vol.41, p.110364, Article 110364
• Main Authors: Chen, Ziheng, Xu, Min, Hu, Tao, Xue, Gang, Chen, Fei, Zhao, Huijun, Zhou, Hao, Lei, Yun, Zhu, Keqian
• Format: Article
• Language: English
• Subjects: CO2-H2S partial pressure; Corrosion; Gas injection-extraction pipeline; Gas storage reservoir; Gum
• ISSN: 2352-4928; 2352-4928
• DOI: 10.1016/j.mtcomm.2024.110364

The effects of H2S content on the corrosion behavior of gas storage reservoir injection and extraction pipeline steel in a CO2-H2S environment were investigated by surface characterization and ultrasonic thickness measurement. The results show that the corrosion products of gas injection and extraction pipelines under real conditions are more complex. In the CO2-H2S environment, with the increase of H2S content, the corrosion rate of gas storage reservoir gas injection and extraction pipeline steel firstly increases and then decreases. At a partial pressure ratio of CO2 to H2S of 550, corrosion resulted mainly in the formation of FeCO3, FeS2, and Fe3O4, with limited generation of stabilizing protective films. This led to severe localized corrosion, mainly driven by CO2. In contrast, when the CO2 to H2S partial pressure ratio was reduced to 5.2, the corrosion mainly produced Fe7S8, FeS2, and BaSO4, which promoted the formation of a more stable protective film on the inner wall of the tube, while the presence of gums reduced the severity of the localized corrosion and shifted the corrosion control to H2S. [Display omitted]