Hysteresis-less mesoscopic CH3NH3PbI3 perovskite hybrid solar cells by introduction of Li-treated TiO2 electrode

• Published in: Nano energy 2015-07, Vol.15, p.530-539
• Main Authors: Heo, Jin Hyuck, You, Myoung Sang, Chang, Min Hyuk, Yin, Wenping, Ahn, Tae Kyu, Lee, Sang-Ju, Sung, Shi-Joon, Kim, Dae Hwan, Im, Sang Hyuk
• Format: Article
• Language: English
• Subjects: Hybrid solar cells; J–V hysteresis; Li-treatment; Methylammoniumleadtriiodide; Perovskite
• ISSN: 2211-2855
• DOI: 10.1016/j.nanoen.2015.05.014

A great current density–voltage (J–V) hysteresis with respect to the scan direction is important issue in perovskite hybrid solar cells because the power conversion efficiency is sometimes incorrect. Here, we demonstrated >17% mesoscopic CH3NH3PbI3 (MAPbI3) perovskite hybride solar cells without significant J–V hysteresis with respective to the scan direction and rated by using Li-treated mesoscopic TiO2 electrode. The Li-treated mesoscopic TiO2 electrode improved charge separation/injection from MAPbI3 into mesoscopic TiO2, charge transport in mesoscopic TiO2, and surface traps because the conduction band edge of mesoscopic TiO2 was lowered by ~0.1eV, the mobility of charge carriers was increased from ~1.1×10−6cm2/Vs to ~2.5×10−6cm2/Vs, the conductivity of mesoscopic TiO2 was increased from ~5.6×10−7S/cm to ~1.6×10−6S/cm, and the trap density was reduced from ~1.2×1016cm−3 to ~9.3×1015cm−3 through Li-treatment. Therefore, the average power conversion efficiency was significantly enhanced from 14.84% to 17.26% at 1sun condition by the Li-treatment of mesoscopic TiO2. [Display omitted] •Hysteresis-free mesoscopic perovskite solar cell by introduction of Li-treated mesoscopic TiO2 electrode.•Improved charge injection and transport by Li-treatment of mesoscopic TiO2