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Optical properties of organic/inorganic nanocomposite sol-gel films containing LaPO4:Er,Yb nanocrystals

The LaPO4:Er,Yb nanocrystals of average particle size about 5–7nm were prepared from solution-based reaction. The nanocrystals were successfully incorporated into the sol-gel organic/inorganic hybrid matrix up to 30wt.% without phase separation. The nanocomposite films showed strong luminescence int...

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Bibliographic Details
Published in:Optical materials 2006-03, Vol.28 (4), p.374-379
Main Authors: Ahn, Bok Yeop, Seok, Sang Il, Hong, Suk-In, Oh, Jae-Seok, Jung, Ha-Kyun, Chung, Woon Jin
Format: Article
Language:English
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Summary:The LaPO4:Er,Yb nanocrystals of average particle size about 5–7nm were prepared from solution-based reaction. The nanocrystals were successfully incorporated into the sol-gel organic/inorganic hybrid matrix up to 30wt.% without phase separation. The nanocomposite films showed strong luminescence intensity in the near infrared region around 1550nm after heat treatment below 150°C. The refractive indices of the composite films were adjustable by controlling both the Zr/Si ratio in the sol-gel hybrid matrices and the contents of the LaPO4:Er,Yb nanocrystals incorporated in the matrices. The propagation loss of the composite films was about 0.5dB/cm, and that was prone to be increased with increasing the contents of the LaPO4:Er,Yb nanocrystals.
ISSN:0925-3467
1873-1252
DOI:10.1016/j.optmat.2005.02.003