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Luminescent hybrid materials based on (8-hydroxyquinoline)-substituted metal-organic complexes and lead-borate glasses

Novel luminescent organic-inorganic hybrid materials based on 8-hydroxyquinoline metal complexes (Liq, Kq, Naq, Rbq, Mgq2, Srq2, Znq2, Scq3, Alq3, Gaq3, and Inq3) have been synthesized by a high temperature exchange reaction with 80PbF2–20B2O3 inorganic low-melting glass. The mechanical and optical...

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Published in:Optical materials 2017-07, Vol.69, p.141-147
Main Authors: Petrova, Olga B., Anurova, Maria O., Akkuzina, Alina A., Saifutyarov, Rasim R., Ermolaeva, Ekaterina V., Avetisov, Roman I., Khomyakov, Andrew V., Taydakov, Ilya V., Avetissov, Igor Ch
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Language:English
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Summary:Novel luminescent organic-inorganic hybrid materials based on 8-hydroxyquinoline metal complexes (Liq, Kq, Naq, Rbq, Mgq2, Srq2, Znq2, Scq3, Alq3, Gaq3, and Inq3) have been synthesized by a high temperature exchange reaction with 80PbF2–20B2O3 inorganic low-melting glass. The mechanical and optical properties, transmission spectra, emission an excitation photoluminescence, and luminescence kinetic of hybrid materials were studied. All hybrid materials showed a wide luminescence band in the range 400–700 nm. [Display omitted] •Luminescent hybrids based on organic metal complexes and fluoroborate glass were made.•Fluoroborate based hybrids are more stable towards oxyborate based hybrids.•Synthesized hybrids showed a wide luminescence band in the range 400–700 nm.
ISSN:0925-3467
1873-1252
DOI:10.1016/j.optmat.2017.04.014