Tunable green/red luminescence by infrared upconversion in biocompatible forsterite nanoparticles with high erbium doping uptake

• Published in: Optical materials 2018-02, Vol.76, p.407-415
• Main Authors: Zampiva, Rúbia Young Sun, Acauan, Luiz Henrique, Venturini, Janio, Garcia, Jose Augusto Martins, da Silva, Diego Silverio, Han, Zhaohong, Kassab, Luciana Reyes Pires, Wetter, Niklaus Ursus, Agarwal, Anuradha, Alves, Annelise Kopp, Bergmann, Carlos Pérez
• Format: Article
• Language: English
• Subjects: Biomaterial; Erbium doping; Forsterite nanoparticles; Tunable emission; Upconversion
• ISSN: 0925-3467; 1873-1252
• DOI: 10.1016/j.optmat.2018.01.004

Nanoparticles represent a promising platform for diagnostics and therapy of human diseases. For biomedical applications, these nanoparticles are usually coated with photosensitizers regularly activated in a spectral window of 530–700 nm. The emissions at 530 nm (green) and 660 nm (red) are of particular interest for imaging and photodynamic therapy, respectively. This work presents the Mg2SiO4:Er3+ system, produced by reverse strike co-precipitation, with up to 10% dopant and no secondary phase formation. These nanoparticles when excited at 985 nm show upconversion emission with peaks around 530 and 660 nm, although excitation at 808 nm leads to only a single emission peak at around 530 nm. The direct upconversion of this biomaterial without a co-dopant, and its tunability by the excitation source, renders Mg2SiO4:Er3+ nanoparticles a promising system for biomedical applications. [Display omitted]