Two novel ESIPT benzothiazol derivatives and corresponding europium(Ⅲ) complexes: Synthesis and fluorescent properties

• Published in: Optical materials 2019-02, Vol.88, p.606-614
• Main Authors: Xiao, Gangxiang, Li, Mei, Luan, Fangfei, Li, Dewei, Li, Guizhi, Kuang, Yongqing, Guo, Dongcai
• Format: Article
• Language: English
• Subjects: Benzothiazol derivative; Electrochemical property; ESIPT; Europium complex; Fluorescence property; Synthesis
• ISSN: 0925-3467; 1873-1252
• DOI: 10.1016/j.optmat.2018.12.037

Two ESIPT benzothiazol derivatives and corresponding europium complexes were synthesized and characterized by the 1HNMR spectrum, Mass spectrum, Elemental analysis, UV–Vis analysis, Molar conductivity, Thermogravimetric analysis and FTIR analysis. The fluorescence intensity of the ligands and complexes are compared, and the fluorescence quantum yields are also calculated by the reference method. The results show that two ligands emit orange fluorescence due to the ESIPT process, but both complexes emit red fluorescence after coordinating with Eu3+. Compared with the ligands, the fluorescence intensity and fluorescence quantum yield of the complexes are enhanced, and the monochromaticity is also improved. Because of the stable tetradentate coordination, the fluorescence intensity of EuL7(NO3)3·2H2O is the strongest, and EuL7(NO3)3·2H2O > EuL6(NO3)3·2H2O > Ligand 6 > Ligand 7, so does the fluorescence quantum yields. The electrochemical properties of the complexes show that the HOMO energy level of EuL7(NO3)3·2H2O is higher than that of EuL6(NO3)3·2H2O, but LUMO energy level is lower than that of EuL6(NO3)3·2H2O. These ligands and complexes have potential applications in the field of life sciences and optical materials. [Display omitted] •Two ESIPT benzothiazol derivatives and their corresponding Eu complexes were synthesized and characterized.•All the ligands emit the orange fluorescence, but complexes emit the characteristic red light of Eu3+.•The relationship between the structure of ligands and the fluorescence intensities of target complexes have been discussed.•The fluorescence and electrochemical properties are compared between the tetradentate and the tridentate coordination complexes.