Dye-sensitized solar cells with aluminum-doped zinc oxide nanoparticles-loaded electrolyte: A breakthrough solution for recombination and hysteresis suppression

• Published in: Optical materials 2023-08, Vol.142, p.113979, Article 113979
• Main Authors: Elbohy, Hytham, Elnemr, Abdel-Menem, Ghander, Ahmed M., El-Sayed, Ibrahim A.
• Format: Article
• Language: English
• Subjects: Dye-sensitized solar cells; Electrolyte; Hysteresis; Recombination suppression
• ISSN: 0925-3467; 1873-1252
• DOI: 10.1016/j.optmat.2023.113979

Dye-sensitized solar cells (DSCs) suffer from reduced power conversion efficiency due to electron recombination with triiodide (I3−) ions at the photoanode/electrolyte interface. Organic additives are conventionally used in electrolyte to reduce recombination and improve the efficiency of the device. These additives react covalently with iodine (I2) in the electrolyte, leading to a reduction in the concentration of I3− ions. Other inorganic oxides, such as silica (SiO2), titania (TiO2), and magnesia (MgO), have been shown to improve the efficiency of the solar cell. These oxides can adsorb heavy ions to some extent. In this study, we investigated aluminum-doped zinc oxide nanoparticles (AZO NPs) as an inorganic additive with ionic adsorption properties towards I− and I3− anions in the electrolyte. We confirmed the ionic adsorption of AZO NPs through zeta potential and electrochemical impedance measurements. We observed a significant decrease in recombination between photogenerated electrons and electrolyte ions after adding AZO NPs, which resulted in an increase in open circuit voltage (VOC) and fill factor (FF) values. Furthermore, the incorporation of AZO NPs reduced the compelled hysteresis caused by the mismatch in current density-voltage curves for the forward and reverse scan direction. Mott-Schottky analysis confirmed the increase in VOC due to the negative shift in the Fermi level of the TiO2 photoanode. Additionally, open circuit voltage decay measurements indicated a longer electron lifetime at the TiO2/electrolyte interface in AZO NPs loaded electrolyte. Our findings suggest that AZO NPs have potential as an effective inorganic additive for improving the performance of DSCs. A schematic diagram of dye sensitized solar cell with electrolyte before and after adding AZO NPs. [Display omitted] •AZO NPs loaded electrolyte retards recombination at TiO2/electrolyte interface.•The adsorption of AZO NPs with ionic characteristics decreases recombination reactions.•The device's hysteresis is considerably reduced by AZO insertion.•The introduction of AZO NPs into the electrolyte leads to an improvement in the device's power conversion efficiency.