Structural and optical characteristics of Cr-doped TiO2 thin films synthesized by sol-gel method

• Published in: Optical materials 2024-05, Vol.151, p.115411, Article 115411
• Main Authors: Prasad, Abhishek, Singh, Fouran, Dhuliya, Vivek, Purohit, L.P., Ramola, R.C.
• Format: Article
• Language: English
• Subjects: Cr-doped TiO2 films; Force constant; Metal-oxygen bond; Optical bandgap; Urbach energy
• ISSN: 0925-3467; 1873-1252
• DOI: 10.1016/j.optmat.2024.115411

In this paper, undoped and 7 %, and 20 % chromium doped titanium dioxide thin films were synthesized on silicon and quartz substrates by utilizing the sol-gel spin coating process. The films were then annealed at 450 °C. The synthesis process and the effects of doping on the structural, optical, and vibrational properties were studied. XRD analysis showed that the undoped thin film had an anatase phase with a crystalline size of about 15.4 nm. However, as the concentration of chromium increased, the crystalline size decreased, and we obtained a mixed phase of rutile and anatase for doped films. The FTIR spectra revealed that undoped films had Ti–O bonding at 435 cm−1 and bond with stretching at 619 cm−1 wavenumbers, which decreased to 379 cm−1 and 377 cm−1 wavenumbers for 7 % and 20 % Cr doping, respectively. The optical measurements showed that the films were homogeneous and had high transmission, reaching 95 % in the visible range for the undoped thin film and 80 % for higher doping levels of chromium. These films have a remarkable level of transparency, and because of that they are highly regarded in the field of thin-film solar cells. Their optical properties make them an excellent choice for use as optical windows in these types of solar cells. As the amount of chromium in the film increases, the optical bandgap decreases from 3.23 eV to 2.26 eV. This suggests that chromium has a significant impact on the optical properties of these films, which might be helpful to researchers and professionals working in the fields of solar energy, optoelectronic devices, photocatalytic systems, gas sensors, and solar cell passivation. •The decrease in crystallinity of TiO2 thin film was observed with the increase of chromium doping.•Increase in chromium doping leads to the reduction in the bandgap of TiO2 thin films.•The chemical bond (619 cm−1) stability in TiO2 thin films increases with increase in chromium doping.