Cu-doped Bi2S3 nanorod films via chemical synthesis for improved photoelectrochemical water splitting

• Published in: Optical materials 2024-11, Vol.157, p.116289, Article 116289
• Main Authors: U., Chalapathi, Cuddapah, Dhananjaya Rao, B., Purusottam Reddy, Alhammadi, Salh, Alshgari, Razan A., Radhalayam, Dhanalakshmi, Golkonda, Srinivas Reddy, Sangaraju, Sambasivam, Mohanarangam, Krithikaa, Minnam Reddy, Vasudeva Reddy, Park, Si-Hyun
• Format: Article
• Language: English
• Subjects: Bi2S3 thin films; Chemical bath deposition; Cu-doping; Microstructure; Nanorods; Water splitting; X-ray diffraction
• ISSN: 0925-3467
• DOI: 10.1016/j.optmat.2024.116289

Bismuth sulfide (Bi2S3) is a promising photoelectrochemical (PEC) material due to its favorable optoelectronic properties. However, its overall PEC performance is limited by slow charge transport and high electron–hole recombination at the Bi2S3-electrolyte interface. In this study, we have intentionally introduced Cu into Bi2S3 photoelectrodes to enhance both their physical properties and PEC performance. Cu-doping concentrations ranging from 0 to 8.4 at.% were incorporated into Bi2S3 films synthesized via chemical bath deposition followed by annealing. The undoped Bi2S3 photoelectrodes exhibited nanorods with lengths of 50–100 nm, a direct bandgap of 1.26 eV, and a photocurrent density of 4.7 mA/cm2 at 1.5 V vs Hg/HgO. As the Cu-doping concentration increased from 1.0 to 4.4 at.%, the nanorod length extended to 200–400 nm, with a corresponding increase in density, leading to an enhanced photocurrent density of 6.8 mA/cm2. However, further increasing the Cu-doping concentration to 8.4 at.% resulted in a reduction in film thickness, nanorod density, and a decrease in photocurrent to 6.0 mA/cm2. These results demonstrate that Cu-doping in Bi2S3 significantly increases nanorod density and improves both the physical and PEC properties, offering a promising approach for developing more efficient PEC water-splitting devices. •Chemical bath deposition of Bi2S3 nanorod films on fluorine-doped tin oxide substrates.•Effect of Cu-doping on the physical and PEC properties of Bi2S3 is investigated.•Low Cu-doping yields pure Bi2S3; high Cu-doping forms Cu1.9375S secondary phase.•Low Cu-doping improved nanorod density and photocurrent from 4.7 to 6.8 mA/cm2.•High Cu-doping decreases nanorod density and photocurrent to 6.0 mA/cm2 in Bi2S3.