An alternative composite electrode for efficient organic light-emitting diodes

• Published in: Organic electronics 2020-10, Vol.85, p.105844, Article 105844
• Main Authors: Luo, Dian, Chiang, Tsung-Che, Chan, Chi-Hao, Chiu, Po-Chen, Chiu, Hao-Hsuan, Ku, Chia-Hao, Chang, Chih-Hao, Guo, Jhih-Yan, Liu, Shun-Wei, Su, Hai-Ching
• Format: Article
• Language: English
• Subjects: Composite electrode; Gallium-doped zinc oxide; Molybdenum-doped GZO (MGZO); Organic light-emitting diode (OLED); Silicon-doped GZO (SGZO)
• ISSN: 1566-1199; 1878-5530
• DOI: 10.1016/j.orgel.2020.105844

Considering a device structure consisting of multi-stacked layers with different refractive indices, we proposed a composite electrode to diminish total internal reflection, thereby improving the out-coupling efficiency of organic light-emitting diodes (OLEDs). The selected transparent conducting oxide materials for the composite electrode were composed of the same main material, gallium-doped zinc oxide (GZO), to avoid lattice mismatch and reduce interfacial strain. Herein, silicon-doped GZO (SGZO) with a relatively low refractive index was used in combination with molybdenum-doped GZO (MGZO) with a high work function to form a multifunctional transparent composite electrode. High transmittance of 94.5% and adequate sheet resistance of 52.3 Ohm/sq were realized through the design of SGZO/MGZO films on a glass substrate. The tested blue phosphorescent OLEDs with SGZO/MGZO composite anode outperformed devices with other selected single-layer electrodes, achieving a high peak efficiency of 29.0% (57.6 cd/A and 47.6 lm/W). These results demonstrate clear advantages of using this composite-electrode concept for realizing high efficiency OLEDs or other flexible optoelectronics. [Display omitted] •SGZO with a relatively low refractive index was used in combination with MGZO with a high work function to form a multifunctional transparent composite electrode.•High transmittance and adequate sheet resistance were realized through the design of SGZO/MGZO films on a glass substrate.•An alternative SGZO/MGZO composite electrode presents a remarkable potential for realizing OLEDs with outstanding EL performance.