The electrical transport property and gas detection behaviour of polyvinyl alcohol and γ-Fe2O3 nanocomposite film

• Published in: Physica. B, Condensed matter Condensed matter, 2024-10, Vol.690, p.416193, Article 416193
• Main Authors: Sinha, Ranjita, Nandi, Tanima, De, Avik, Halder, Monalisa, Raul, Chandan Kumar, Sarkar, Santu, Haldar, Sandip
• Format: Article
• Language: English
• Subjects: Electrical conduction mechanism; Gas detection mechanism; Iron oxide nanoparticles; Nanocomposite film
• ISSN: 0921-4526
• DOI: 10.1016/j.physb.2024.416193

This paper presents the electrical and gas detection behaviour of polyvinyl alcohol (PVA)/γ-Fe2O3 nanocomposite films. The physical characterization includes X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDX), and UV–Visible spectroscopy. The analysis of both the dc resistivity and ac conductivity using Correlated Barrier Hoping (CBH) conduction process shows that the conductivity enhances with the decreasing of activation energy in case of the PVA/γ-Fe2O3 nanocomposite film which is the indication of interfacial defect states. The current voltage study at various temperatures follows the thermoionic emission model of Schottky Barrier diode. Moreover, the dielectric constant enhances for PVA/γ-Fe2O3 nanocomposite film, which indicates homogeneous distribution of γ-Fe2O3 nanoparticles within PVA matrix and the aggregation of trapped charges found in interface develops an interfacial polarization. As a result, the gas adsorption capacity of the nanocomposite film increases which improves the signal-to-noise ratio, leading to higher gas detection sensitivity.