Technology ready use of single layer graphene as a transparent electrode for hybrid photovoltaic devices

• Published in: Physica. E, Low-dimensional systems & nanostructures Low-dimensional systems & nanostructures, 2011-11, Vol.44 (2), p.521-524
• Main Authors: Wang, Zhibing, Puls, Conor P., Staley, Neal E., Zhang, Yu, Todd, Aaron, Xu, Jian, Howsare, Casey A., Hollander, Matthew J., Robinson, Joshua A., Liu, Ying
• Format: Article
• Language: English
• Subjects: Applied sciences; Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.); Cross-disciplinary physics: materials science; rheology; Electronics; Energy; Exact sciences and technology; Fullerenes and related materials; diamonds, graphite; Materials science; Methods of deposition of films and coatings; film growth and epitaxy; Molecular electronics, nanoelectronics; Natural energy; Photovoltaic conversion; Physics; Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices; Solar cells. Photoelectrochemical cells; Solar energy; Specific materials
• ISSN: 1386-9477; 1873-1759
• DOI: 10.1016/j.physe.2011.10.003

Graphene has been used recently as a replacement for indium tin oxide (ITO) for the transparent electrode of an organic photovoltaic device. Due to its limited supply, ITO is considered as a limiting factor for the commercialization of organic solar cells. We explored the use of large-area graphene grown on copper by chemical vapor deposition (CVD) and then transferred to a glass substrate as an alternative transparent electrode. The transferred film was shown by scanning Raman spectroscopy measurements to consist of >90% single layer graphene. Optical spectroscopy measurements showed that the layer-transferred graphene has an optical absorbance of 1.23% at a wavelength of 532 nm. We fabricated organic hybrid solar cells utilizing this material as an electrode and compared their performance with those of ITO devices fabricated using the same procedure. We demonstrated power conversion efficiency up to 3.98%, higher than that of the ITO device (3.86%), showing that layer-transferred graphene promises to be a high quality, low-cost, flexible material for transparent electrodes in solar cell technology. ► We use CVD-grown graphene films as transparent electrodes in photovoltaic devices. ► Graphene is >90% monolayer with 1.23% absorbance at a wavelength of 532 nm. ► We demonstrate power conversion efficiency up to 3.98%. ► Graphene-based devices perform better than those based on indium tin oxide.