Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene

• Published in: Polyhedron 2017-10, Vol.135, p.96-100
• Main Authors: Fomenko, Yakov S., Gushchin, Artem L., Tkachev, Aleksey V., Vasilyev, Evgene S., Abramov, Pavel A., Nadolinny, Vladimir A., Syrokvashin, Mikhail M., Sokolov, Maxim N.
• Format: Article
• Language: English
• Subjects: Chiral ligands; Crystal structure; EPR; Oxido complexes; Vanadium
• ISSN: 0277-5387
• DOI: 10.1016/j.poly.2017.07.003

Reactions of VCl3 with chiral derivatives of dihydrophenanthroline (L1) and diazafluorene (L2) result in oxo complexes of V(III) and V(IV) which are further transformed to V(V) complexes in coordinating solvents. The [VVO(L1)(OMe)Cl2] complex was isolated from methanol and characterized by XRD analysis and represent the first oxovanadium complex with chiral diimine ligand. [Display omitted] Reactions of VCl3 with chiral derivatives of dihydrophenanthroline (2R,4R,9R,11R)-3,3,10,10-tetramethyl-1,2,3,4,6,7,9,10,11,12-decahydro-2,4:9,11-dimethanodibenzo[b,j][1,10]phenanthroline (L1) and diazafluorene (1R,3R,8R,10R)-2,2,9,9-tetramethyl-2,3,4,7,8,9,10,12-octahydro-1H-1,3:8,10-dimethanocyclopenta[1,2-b:5,4-b′]diquinoline (L2) in acetonitrile in air yield mixtures of [VIII(L1/L2)(CH3CN)Cl3] and [VIVO(L1/L2)(CH3CN)Cl2] (I, II) which were characterized by elemental analysis, IR spectroscopy and magnetic susceptibility data. The behavior of these mixtures in different solvents was investigated by 51V NMR and EPR spectroscopies as well as optical rotation. Recrystallization of a [VIII(L1)(CH3CN)Cl3]/[VIVO(L1)(CH3CN)Cl2] mixture from CH2Cl2/Et2O affords a V(IV) complex, [VIVO(L1)(H2O)Cl2]·nCH2Cl2 (III). Recrystallization from MeOH/Et2O leads to complete oxidation to V(V) complex [VVO(L1)(OMe)Cl2] (IV), which was characterized by X-ray crystallography, IR, 51V and 1H NMR spectroscopies.