Synthesis of carborane-containing carbonates via CO2 addition to epoxides

A new method for the synthesis of carborane-containing carbonates by the reaction of CO2 with the corresponding epoxides was developed. The reaction can be facilitated by an additional hydroxyl group in the catalyst. The crystal structure of 1-phenyl-2-(1,3-dioxolan-2-onylmethyl)-C2B10H10 was determ...

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Bibliographic Details
Published in:Polyhedron 2021-11, Vol.208, p.115418, Article 115418
Main Authors: Lyubimov, Sergey E., Olshevskaya, Valentina A., Zaitsev, Andrei V., Korlyukov, Alexander A., Zvinchuk, Anastasia A., Cherkasova, Polina V., Chowdhury, Biswajit
Format: Article
Language:English
Subjects:
Carbonates
Carboranes
CO2
Epoxides
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Summary:A new method for the synthesis of carborane-containing carbonates by the reaction of CO2 with the corresponding epoxides was developed. The reaction can be facilitated by an additional hydroxyl group in the catalyst. The crystal structure of 1-phenyl-2-(1,3-dioxolan-2-onylmethyl)-C2B10H10 was determined by single crystal X-ray diffraction. [Display omitted] A new method for the synthesis of carborane-containing carbonates by the reaction of CO2 with the corresponding epoxides was developed. The reaction can be facilitated by an additional hydroxyl group in the catalyst. The crystal structure of 1-phenyl-2-(1,3-dioxolan-2-onylmethyl)-C2B10H10 was determined by single crystal X-ray diffraction. The carborane-containing carbonates can be considered as precursors for the synthesis of advanced heat- and impact-resistant polycarbonates and agents for boron neutron capture therapy.
ISSN:0277-5387
DOI:10.1016/j.poly.2021.115418