Thermochromism in a dinuclear copper complex by spin state changes at various temperatures

Thermochromism in a dinuclear copper complex was assessed by spin state changes and colour changes at various temperatures. [Display omitted] •A dinuclear Cu complex was synthesized and characterized.•The complex shows thermochromism in the solid state.•The complex does not show structural change de...

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Bibliographic Details
Published in:Polyhedron 2022-01, Vol.211, p.115540, Article 115540
Main Authors: Hamaguchi, Tomohiko, Matsuda, Yutaro, Satomi, Naoki, Ishikawa, Ryuta, Hayami, Shinya, Ando, Isao, Kawata, Satoshi
Format: Article
Language:English
Subjects:
DFT
Magnetic susceptibility
Spin state
Thermochromic behavior
X-ray
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Summary:Thermochromism in a dinuclear copper complex was assessed by spin state changes and colour changes at various temperatures. [Display omitted] •A dinuclear Cu complex was synthesized and characterized.•The complex shows thermochromism in the solid state.•The complex does not show structural change depends on the temperature.•The thermochromism was assessed by TD-DFT calculation.•Spin state change at various temperatures would cause the thermochromism. This study explored the thermochromic behavior of [(μ2-6-methyl-2-pyridinemethanolate)2{Cu(6-methyl-2-pyridinemethanol)}2](PF6)2. The complexes show no significant variation between 296 K and 100 K according to a single-crystal X-ray crystallographic investigation. The occupancy of the triplet at 300 K and 100 K is 55% and 16.9%, respectively based on magnetic susceptibility. Photographs of the complex at different temperatures and quantum calculation exhibit that the thermochromic behavior is induced by the alteration of spin state between triplet and singlet.
ISSN:0277-5387
DOI:10.1016/j.poly.2021.115540