Synthesis of CuO nanosheets on Cu foil via one-step wet chemical process at different reaction temperatures and their photoelectrochemical performance

• Published in: Polyhedron 2024-10, Vol.261, p.117156, Article 117156
• Main Authors: Guitoume, Djamal Eddine, Daamouche, Mosbah, Lahmar, Halla, Ababsa, Abdelmadjid, Bouheroum, Sofiane, Boudissa, Mokhtar, Farh, Hichem, Merabti, Halim
• Format: Article
• Language: English
• Subjects: Copper oxidation; CuO; Nanostructures; Photocathode
• ISSN: 0277-5387
• DOI: 10.1016/j.poly.2024.117156

[Display omitted] Cupric oxide (CuO) nanostructures were directly grown on copper substrate via a simple one step solution-immersion process. The films were formed by the direct oxidation of copper in aqueous solution containing sodium hydroxide (NaOH) and ammonium persulfate (NH4)2S2O8. The influence of the reaction temperature on the structural, morphological, optical and photoelectrochemical (PEC) properties of the formed copper compounds nanostructures was investigated. The XRD and Raman spectroscopy results revealed the formation of Cu(OH)2/CuO composite for the samples prepared at 3 and 25 °C, and pure CuO was obtained for the samples prepared at 45 and 55 °C. The SEM micrographs showed that the formed Cu(OH)2 and CuO present a nanowire bundles and nanosheet morphology, respectively. The increase of the reaction temperature enhanced the absorbance of the CuO samples in the entire visible region. According to the photoelectrochemical measurements, the increase of the reaction temperature resulted in an improvement of the PEC response. The CuO nanosheets synthesized at 55 °C presents the highest and the most stable PEC response. A reasonable mechanism describing the formation of nanostructured copper compounds at different reaction temperatures is discussed in this paper.