Electrodeposition of polyaniline on reduced graphene oxide/cotton yarn with tunable electrochemical performance for flexible textile supercapacitors

• Published in: Polymer (Guilford) 2024-06, Vol.306, p.127200, Article 127200
• Main Authors: Li, Lin, Du, Dou, He, Chengen, Han, Kun, Xu, Weilin, Xia, Liangjun, Cai, Guangming, Cui, Xun, Chen, Yihuang, Yu, Lianqing, Kong, Lingxue
• Format: Article
• Language: English
• Subjects: Electrodeposition; Flexible textile supercapacitor; PANI; RGO; Tunable electrochemical performance
• ISSN: 0032-3861; 1873-2291
• DOI: 10.1016/j.polymer.2024.127200

Graphene/cotton fibers show significant promise in wearable energy storage due to their low cost, porous structure, and exceptional integration ability into wearable systems. However, the eco-unfriendly reductants and standalone electric double-layer capacitor hindered their application. Herein, a green and rapid hydrothermal-electrodeposition method was proposed to fabricate polyaniline (PANI) decorated reduced graphene oxide (rGO)/cotton yarns without using any chemical reductants and oxidants. The PANI/rGO/cotton (PRC) yarn exhibited porous conductive network, structural controllability, and mechanical flexibility. Additionally, the PRC yarn electrode delivers a fast electron transport and ion migration, synergistic energy storage contribution, and a controllable capacitance (up to 81.2 mF cm−1 at 0.2 mA cm−1). The assembled yarn supercapacitor shows a good capacitance (19.8 mF cm−1 at 0.08 mA cm−1), excellent energy-power density (2.7 μWh cm−1 at 40 μW cm−1), and great capacitance retention. This green fabrication of PRC yarns brings new insights into the development of wearable energy storage. [Display omitted] •Polyaniline/reduced graphene oxide/cotton (PRC) composite yarn was made.•A green and rapid hydrothermal-electrodeposition method was proposed.•PRC yarn shows porous conductive network, structural controllability, and flexibility.•PRC yarn electrode shows fast electron/ion transport and synergistic capacitance.•PRC yarn supercapacitor shows good specific capacity, power density and cycle ability.