Synthesis, characterization and properties of vinyl-terminated poly[dimethylsiloxane-co-methyl(phenyl)siloxane]

• Published in: Polymer (Guilford) 2024-10, Vol.311, p.127554, Article 127554
• Main Authors: Wang, Shengqiang, Peng, Zhenbo, Huang, Yanhua, Zhu, Mingquan, Liu, Yayun, Zhang, Yong
• Format: Article
• Language: English
• Subjects: Copolymerization; Crystalline; Low-temperature resistance; Poly [dimethylsiloxane-co-methyl (phenyl)siloxane]; Thermal stability
• ISSN: 0032-3861
• DOI: 10.1016/j.polymer.2024.127554

Phenyl-containing polysiloxanes have better thermal stability, low-temperature flexibility, and room-temperature damping performance than polydimethylsiloxanes. Poly [dimethylsiloxane-co-methyl (phenyl)siloxane] and poly (dimethylsiloxane-co-diphenylsiloxane) were synthesized through a bulk copolymerization of octamethylcyclotetrasiloxane and methylphenylcyclosiloxane mixture or octaphenylcyclotetrasiloxane, and the structure and properties of the copolysiloxanes were comparatively studied. The phenyl content in poly [dimethylsiloxane-co-methyl (phenyl)siloxane] can be as high as 50 mol%. With the increment of the phenyl content, the thermal stability of the copolysiloxanes is dramatically improved as evaluated by thermal gravimetric analysis. At a given phenyl content, poly [dimethylsiloxane-co-methyl (phenyl)siloxane] has higher thermal stability than poly (dimethylsiloxane-co-diphenylsiloxane). The former is more difficult to crystalline at low temperatures and has lower room temperature viscosity than the latter as confirmed by differential scanning calorimetry and rotational rheometer. The copolysiloxanes is mixed with hydrogen-containing polysiloxane and silica, and vulcanized at elevated temperature to get copolysiloxane composites with good damping properties, oil resistance, and low-temperature resistance. This study not only enriches the fundamental academic research on functional polysiloxanes, but also provides useful technical references for practical applications of phenyl silicone rubber. [Display omitted] •Poly (dimethylsiloxane-co-methylphenylsiloxane) with a phenyl content of 50 mol% can be obtained by bulk homopolymerization.•Revealing the effects of the −MePhSiO− and −Ph2SiO− units on sequence, crystallization, thermal stability and viscosity.•Silicone rubber composites based on poly (dimethylsiloxane-co-methylphenylsiloxane) have superior low temperature resistance.