Exploitation of tannic acid as additive for the adhesion enhancement of UV-curable bio-based coating

• Published in: Progress in organic coatings 2024-04, Vol.189, p.108311, Article 108311
• Main Authors: Sesia, Rossella, Cardone, Anna Giulia, Ferraris, Sara, Spriano, Silvia, Sangermano, Marco
• Format: Article
• Language: English
• Subjects: Adhesion; Bio-based coating; Epoxidized soybean oil; Photopolymerization; Tannic acid
• ISSN: 0300-9440; 1873-331X
• DOI: 10.1016/j.porgcoat.2024.108311

The interest in environmentally friendly coatings is rising to substitute for the oil-derived materials in the coating industry. In the present study, natural tannic acid (TA) is investigated as an additive to an epoxidized soybean oil-based (ESO) coating. TA solutions in propylene carbonate at two different concentrations were prepared and added to an ESO matrix with different weight ratios. The UV-curing process of the coatings was deeply assessed through real-time Fourier Transform Infrared (FTIR) spectroscopy and Differential Scanning photo Calorimetry (photo-DCS). A significant increase in high epoxy group conversion, around 90 %, was achieved thanks to the activated monomer mechanism, which involves the TA polyphenols. This mechanism accelerated the photocrosslinking process, but reduced the coatings' crosslinking density, as demonstrated by the dynamic thermal mechanical analysis. The hardness of coatings containing the TA additive decreased, while the hydrophobicity of the surface coatings remained unchanged after the TA incorporation. Lastly, the adhesion of the UV-cured coating was evaluated on low-carbon steel substrates. An outstanding enhancement in adhesion property was provided by the TA additive, whose phenols not only participate in the photocrosslinking reaction but also coordinate iron on the steel surface. Moreover, the influence of two different steel surface pre-treatments, the pickling and plasma processes, on the coatings' adhesion strength was studied.