Polymers Based on Norbornene Derivatives

This study presents the influence of exo,exo-N,N’- hexylene-di(5-norbornene-2,3-dicarboximide) on the degree of cross-linking and glass transition temperature of the polymers obtained from a mixture of dimethyl esters of exo,exo- and endo,endo-5-norbornene-2,3-dicarboxylic acid. It was found that ex...

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Bibliographic Details
Published in:Procedia chemistry 2015, Vol.15, p.8-13
Main Authors: Bozhenkova, G.S., Samochernova, A.P., Ashirov, R.V., Lyapkov, A.A.
Format: Article
Language:English
Subjects:
cross-linking
gel content
metathesis
norbornene derivatives
ROMP
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Summary:This study presents the influence of exo,exo-N,N’- hexylene-di(5-norbornene-2,3-dicarboximide) on the degree of cross-linking and glass transition temperature of the polymers obtained from a mixture of dimethyl esters of exo,exo- and endo,endo-5-norbornene-2,3-dicarboxylic acid. It was found that exo,exo-N,N’- hexylene-di(5-norbornene-2,3-dicarboximide) can be used as a cross-linking agent in ROMP. Addition of the cross-linking agent leads to an increase in the degree of cross-linking polymers. The glass transition temperature of polymers increases with concentration increasing of the crosslinking agent.
ISSN:1876-6196
1876-6196
DOI:10.1016/j.proche.2015.10.002