Characterization of Ce-doped lithium borosilicate glasses as tissue-equivalent phosphors for radiation measurements

• Published in: Radiation measurements 2018-04, Vol.111, p.13-18
• Main Authors: Isokawa, Yuya, Hirano, Shotaro, Okada, Go, Kawaguchi, Noriaki, Yanagida, Takayuki
• Format: Article
• Language: English
• Subjects: Cerium; Dosimeter; Glass; Lithium borosilicate; Scintillation
• ISSN: 1350-4487; 1879-0925
• DOI: 10.1016/j.radmeas.2018.02.009

We synthesized lithium borosilicate glasses doped with different concentrations of Ce (0.01%, 0.03%, 0.10%, and 0.30%) as well as undoped glass, and then the prepared glasses were studied for their optical, dosimetric, and scintillation properties. The Ce-doped samples exhibited scintillation and photoluminescence (PL) due to the 5d–4f transitions of Ce3+, with broad spectral features peaking around 350 nm. The PL and scintillation decay times were 30.7–31.6 ns and 64–82 ns, respectively. As the concentration of Ce increased, the scintillation intensity increased. Among the present samples, the 0.03% Ce-doped sample showed the highest PL quantum yield (9.7%). The quantum yield was well correlated with the decay time. In addition, thermally stimulated luminescence was observed after irradiation with X-rays. The sensitivity was highest for the 0.10% Ce-doped sample, having a dynamic range from 0.05 mGy to 10 Gy, which was equivalent to that of commercial dosimeters. Furthermore, the thermally stimulated luminescence spectrum was due to the 5d–4f transitions of Ce3+. The concentration of Ce that gave the highest sensitivity was 0.10%. •Ce-doped lithium borosilicate glasses were synthesized by the melt-quenching method.•Scintillation, PL and TSL emissions were predominantly due to the 5d-4f transitions of Ce3+.•Ce-doped lithium borosilicate glasses showed sensitive TSL response to X-ray dose.•Dynamic range as TSL dosimeter was confirmed to be at least 0.05 mGy–10 Gy.