Preparation of thiol–ene porous polymers by emulsion templating

Emulsion-templated porous polymeric materials are prepared by thermal thiol–ene reaction. The right choice of a non-methacrylate trivinyl monomer allows obtaining rigid monoliths with a total porosity of 80% and having the expected polyHIPE morphology.

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Bibliographic Details
Published in:Reactive & functional polymers 2012-12, Vol.72 (12), p.962-966
Main Authors: Sergent, Benoit, Birot, Marc, Deleuze, Hervé
Format: Article
Language:English
Subjects:
Monolith
polyHIPE
Thiol–ene polymerization
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Description
Summary:Emulsion-templated porous polymeric materials are prepared by thermal thiol–ene reaction. The right choice of a non-methacrylate trivinyl monomer allows obtaining rigid monoliths with a total porosity of 80% and having the expected polyHIPE morphology.
ISSN:1381-5148
DOI:10.1016/j.reactfunctpolym.2012.02.011