Investigation into the hydrogen inhibition mechanism of Platycladus orientalis leaf extract as a biodegradation inhibitor for waste aluminum-silicon alloy dust in wet dust collectors

• Published in: Renewable energy 2024-11, Vol.235, p.121376, Article 121376
• Main Authors: Hao, Tengteng, Xu, Kaili, Wang, Haojie, Zheng, Xin, Li, Jishuo, Yu, Yanwu, Liu, Zhenhua
• Format: Article
• Language: English
• Subjects: Hydrogen inhibition; Molecular simulations; Platycladus orientalis leaf extract; Renewable inhibitor; Waster Al-Si dust
• ISSN: 0960-1481
• DOI: 10.1016/j.renene.2024.121376

This study investigates the risk of hydrogen explosion caused by waste metal dust encountering water in wet dust collectors. It proposes using renewable plant extracts to suppress hydrogen evolution from aluminum-silicon (Al-Si) alloy dust, aiming to achieve intrinsically safer production. Platycladus orientalis leaf extract (POLE) was prepared using water as a solvent. Hydrogen inhibition experiments, material characterization, and theoretical calculations were conducted to evaluate the effect of POLE on waste Al-Si dust. The inhibition experiments demonstrated that POLE exhibits excellent inhibitory performance. At a POLE concentration of 2.0 g/L, the hydrogen inhibition efficiency reaches 97.71 % after 22 h, with a reaction rate constant of 8.9708 × 10−5, approaching zero. This efficiency remained stable over 5 days. POLE formed a uniform, dense protective film on the Al-Si dust surface, with a contact angle of 99.23°. FTIR spectra revealed absorption peaks corresponding to POLE functional groups and Al-O bonds, indicating that successfully adsorption of POLE through both physical and chemical interactions. Finally, theoretical calculations were performed to further explain the hydrogen inhibition mechanism of POLE, supplementing and confirming the characterization data. This study inhibited hydrogen production from waste dust, offering a new approach to enhancing the hydrogen production rate from recycled Al scraps. [Display omitted]