The manganese(III) complex with chelating Schiff base ligand: X-ray structure, spectroscopic and computational studies

A new Mn(III) complex, [MnCl(H 2O)(L)]·H 2O·C 2H 5OH, where L = 2,2′-{1,2-phenylenebis[nitrilomethylylidene]}bis(6-methoxyphenolate), has been synthesized and characterized by single-crystal X-ray diffraction. There is a good agreement between calculated and experimental structural data. The complex...

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Bibliographic Details
Published in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2010, Vol.75 (1), p.453-457
Main Authors: Eltayeb, Naser E., Teoh, Siang G., Kusrini, Eny, Adnan, Rohana, Fun, H.K.
Format: Article
Language:English
Subjects:
Computational
Manganese
Schiff base complex
X-ray structure
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Summary:A new Mn(III) complex, [MnCl(H 2O)(L)]·H 2O·C 2H 5OH, where L = 2,2′-{1,2-phenylenebis[nitrilomethylylidene]}bis(6-methoxyphenolate), has been synthesized and characterized by single-crystal X-ray diffraction. There is a good agreement between calculated and experimental structural data. The complex is crystallized in orthorhombic with space group Pbca. The Mn1 atom is coordinated with one Schiff base ligand, one water molecule and one chloride anion, forming a six-coordination number. The electronic and fluorescence spectra of the complex were also studied.
ISSN:1386-1425
DOI:10.1016/j.saa.2009.11.006