Measurement of tyre-based microplastics using traditional and quantum cascade laser-based infrared spectrometry

• Published in: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2025-02, Vol.327, p.125321, Article 125321
• Main Authors: Román-Zas, Cristina, Ferreiro, Borja, Terán-Baamonde, Javier, Estela Del Castillo Busto, M., Andrade, José M., Muniategui, Soledad
• Format: Article
• Language: English
• Subjects: Attenuated total reflectance; Infrared spectrometry; LDIR; Reflectance; Transflectance; Tyre wear particles
• ISSN: 1386-1425
• DOI: 10.1016/j.saa.2024.125321

[Display omitted] •Quantum cascade laser infrared source is proposed first time to study tyre particles.•Tyres can be identified and characterized up to 20 µm.•Major fragments can be determined using ATR measurements.•The information was used to chemometrically differentiate different tyres. Despite the potential environmental impact of TWPs (tyre wear particles), there is a lack of reliable analytical methodologies suitable for their routine identification and characterization. The number of papers dealing with this topic is, so far, very reduced and, therefore, there is a need for addressing it, mostly because traditional transmittance-based IR techniques are suboptimal due to scattering caused by black carbon in tyres. This study aims to evaluate the most appropriate infrared (IR) spectrometric technique for monitoring TWPs. Macro attenuated total reflectance (ATR), reflectance microscopy, and quantum cascade laser-based micro transflectance (QCL-LDIR) were employed to analyse samples from used car and truck tyres in two sample configurations: small tyre fragments (∼1 cm2) and TWPs (< 1 mm). ATR yielded well-defined spectra with good signal-to-noise ratios, allowing for a straightforward interpretation of the major functional moieties. Despite reflectance measurements on tyre fragments provided good results, those on TWPs offered limited information due to noise and scattering. Transflectance offered clear peaks and enhanced resolution in the fingerprint region –compared to the other techniques-, much faster analysis times and the ability to effectively measure particles down to 20–10 µm, thus, emerging as the most effective technique for TWPs analysis. However, spectral interpretation is not immediate. Further, a proof-of-concept chemometric study was done to evaluate whether the analytical techniques contain information to differentiate types of tyres. An unsupervised pattern recognition and a supervised classification technique (principal components analysis and classification trees, respectively) were used, which were able to differentiate among the tyres, notably the truck tyre from the cars tyres. The study presents first time the use of micro transflectance IR to study tyre particles down to 20 µm. Traditional total attenuated reflectance is demonstrated as a suitable way to analyse bigger microplastics. These two options open pathways to monitor this important emerging contaminant in environmental matrices.