A comparative study of the enhancement of molecular emission in a spatially confined plume through optical emission spectroscopy and probe beam deflection measurements

• Published in: Spectrochimica acta. Part B: Atomic spectroscopy 2013-01, Vol.79-80, p.44-50
• Main Authors: Ding, Dayu, Liang, Peipei, Wu, Jiada, Xu, Ning, Ying, Zhifeng, Sun, Jian
• Format: Article
• Language: English
• Subjects: Emission enhancement; Optical emission spectroscopy; Probe beam deflection; Shock wave; Spatial confinement
• ISSN: 0584-8547; 1873-3565
• DOI: 10.1016/j.sab.2012.11.005

The spatial confinement effects of shock wave on the expansion of a carbon plume induced by pulsed laser ablation of graphite in air and the enhancement of the plume emission were studied by optical emission spectroscopy and probe beam deflection measurements. A metal disk was set in the way of the ablation-generated shock wave to block and reflect the supersonically propagating shock wave. The reflected shock wave propagated backwards and confined the expanding plume. The optical emission of CN molecules was enhanced in contrast to the case without the block disk and the emission enhancement was dependent on the position of the disk. Based on the results of time-integrated and -resolved optical emission spectroscopy, and the time- and space-resolved probe beam deflection measurements, the processes occurring in the plume were discussed and the mechanisms responsible for the enhancement of molecular emission in the spatially confined plume were investigated. ► Spatial confinement and optical emission enhancement of carbon plume were studied. ► Ablation-generated shockwave propagating in air was reflected by a block disk. ► The effects of reflected shockwave on the emission enhancement were confirmed. ► The reflect shockwave confined the carbon plume and enhanced the plume emission.