Determination of tin isotope ratios in cassiterite by femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry

• Published in: Spectrochimica acta. Part B: Atomic spectroscopy 2017-04, Vol.130, p.26-34
• Main Authors: Schulze, Marie, Ziegerick, Marco, Horn, Ingo, Weyer, Stefan, Vogt, Carla
• Format: Article
• Language: English
• Subjects: Archaeometry; Cassiterite; Laser ablation; MC-ICP-MS; Sn isotope ratios
• ISSN: 0584-8547; 1873-3565
• DOI: 10.1016/j.sab.2017.02.002

In comparison to isotope analysis of dissolved samples femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry (fs-LA-MC-ICP-MS) enables precise isotope ratio analyses consuming much less sample material and with a minimum effort in sample preparation. This is especially important for the investigation of valuable historical objects for which visual traces of sampling are unwanted. The present study provides a basis for tin isotope ratio measurements using LA-MC-ICP-MS technique. For this, in house isotope standards had to be defined. Investigations on interferences and matrix effects illustrate that beside Sb only high Te contents (with values above those to be expected in cassiterite) result in a significant shift of the measured tin isotope ratios. This effect can partly be corrected for using natural isotope abundances. However, a natural isotope fractionation of Te cannot be excluded. Tin beads reduced from cassiterite were analysed by laser ablation and after dissolution. It was shown that tin isotope ratios can be determined accurately by using fs-LA-MC-ICP-MS. Furthermore the homogeneity of tin isotope ratios in cassiterite was proven. [Display omitted] •Tin isotope ratios determined with high precision•Minimal sample preparation•Minimal interferences for cassiterite samples•Precision comparable to analysis of liquids