Estimation of radiative forcing and heating rate based on vertical observation of black carbon in Nanjing, China

• Published in: The Science of the total environment 2021-02, Vol.756, p.144135, Article 144135
• Main Authors: Shi, Shuangshuang, Zhu, Bin, Lu, Wen, Yan, Shuqi, Fang, Chenwei, Liu, Xiaohui, Liu, Duanyang, Liu, Chao
• Format: Article
• Language: English
• Subjects: Black carbon aerosols; Heating rate; Radiative forcing; Vertical profiles
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2020.144135

Owing to a lack of vertical observations, the impacts of black carbon (BC) on radiative forcing (RF) have typically been analyzed using ground observations and assumed profiles. In this study, a UAV platform was used to measure high-resolution in-situ vertical profiles of BC, fine particles (PM2.5), and relevant meteorological parameters in the boundary layer (BL). Further, a series of calculations using actual vertical profiles of BC were conducted to determine its impact on RF and heating rate (HR). The results show that the vertical distributions of BC were strongly affected by atmospheric thermodynamics and transport. Moreover. Three main types of profiles were revealed: Type I, Type II, Type III, which correspond to homogenous profiles (HO), negative gradient profiles (NG), and positive gradient profiles (PG), respectively. Types I and II were related to the diurnal evolution of the BL, and Type III was caused by surrounding emissions from high stacks and regional transport. There were no obvious differences in RF calculated for HO profiles and corresponding surface BC concentrations, unlike for NG and PG profiles. RF values calculated using surface BC concentrations led to an overestimate of 13.2 W m−2 (27.5%, surface) and 18.2 W m−2 (33.4%, atmosphere) compared to those calculated using actual NG profiles, and an underestimate of approximately 15.4 W m−2 (35.0%, surface) and 16.1 W m−2 (29.9%, atmosphere) compared to those calculated using actual PG profiles. In addition, the vertical distributions of BC HR exhibited clear sensitivity to BC profile types. Daytime PG profiles resulted in a positive vertical gradient of HR, which may strengthen temperature inversion at high altitudes. These findings indicate that calculations that use BC surface concentrations and ignore the vertical distribution of BC will lead to substantial uncertainties in the effects of BC on RF and HR. [Display omitted] •Three main types of BC profiles were revealed in Nanjing.•Vertical profiles of BC were affected by atmospheric thermodynamics and transport.•Influences from vertical profiles of BC on radiative forcing and heating rate are discussed.