Contaminant characterization at pesticide production sites in the Yangtze River Delta: Residue, distribution, and environmental risk

• Published in: The Science of the total environment 2023-02, Vol.860, p.160156, Article 160156
• Main Authors: Li, Mei, Chen, Qiang, Yang, Lu, Zhang, Ya, Jiang, Jinlin, Deng, Shaopo, Wan, Jinzhong, Fan, Tingting, Long, Tao, Zhang, Shengtian, Lin, Yusuo
• Format: Article
• Language: English
• Subjects: Benzene; BTEX; CAHs; Environmental Monitoring; Groundwater - chemistry; Groundwater contamination; Pesticides; Pesticides - analysis; Rivers - chemistry; Soil; Soil permeability; Spatial distribution; Toluene; Water Pollutants, Chemical - analysis; Xylenes
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2022.160156

The Yangtze River Delta (YRD) is the largest pesticide-producing region in the world. Contamination of pesticide production sites has always been a focus of public attention. Twenty pesticide production sites in YRD were selected to analyze the residue, distribution, and environmental risk of organic contaminants in soil and groundwater. A total of 194 organic chemicals were detected in all soil and groundwater samples from the 20 sites. Eighty-eight constituents of concern (COCs) exceeded the comparison values of Regional Screening Levels (RSLs), and 80 % exceeded the RSLs by more than five times. The toxic effects of COCs in soil and groundwater were dominated by the carcinogenic risk, referred as “non-threshold”. Benzene toluene ethylbenzene & xylene (BTEX) and chloroaliphatic hydrocarbons (CAHs) were the most prevalent at pesticide sites in YRD rather than pesticides, followed by chlorobenzene, chlorophenols, and polycyclic aromatic hydrocarbons (PAHs). CAHs and BTEX could penetrate up to 24 m, while the others were primarily limited to 12 m. Most pesticide production sites showed a great contamination depth of >8 m, some even deeper than 20 m, posing a great risk of contamination to the confined aquifer. Due to the close interconnection of soil with water bodies, the shallow groundwater and adjacent surface water resources are also susceptible to suffering from environmental risk. More than half of the pesticide production sites in the YRD consist primarily of low-permeable clay layers, making in-situ contamination remediation difficult. This study provides a basis for developing remediation technology for pesticide sites in YRD and an ecological reference for further cleaning production and green manufacturing in the pesticide industry. [Display omitted] •CAHs and BTEX were most prevalent at pesticide sites in YRD rather than pesticides.•Great depths and areas of contamination and the influence factors were analyzed.•Groundwater and adjacent surface water were susceptible for contamination in YRD.•Over 50 % of pesticide sites in YRD consist primarily of low-permeable clay layers.