Adsorption and capacitive regeneration of nitrate using inverted capacitive deionization with surfactant functionalized carbon electrodes

• Published in: Separation and purification technology 2018-04, Vol.194, p.410-415
• Main Authors: Oyarzun, Diego I., Hemmatifar, Ali, Palko, James W., Stadermann, Michael, Santiago, Juan G.
• Format: Article
• Language: English
• Subjects: Chemical surface charge; Inverted capacitive deionization; Nitrate removal; Surfactant treatment
• ISSN: 1383-5866; 1873-3794
• DOI: 10.1016/j.seppur.2017.11.027

[Display omitted] •An inverted capacitive deionization cell for nitrate removal.•An asymmetric cell with high capacity, surfactant-treated electrodes.•Two orders of magnitude higher energy efficiency compared to our Faradaic cell. Nitrate is a pollutant present in groundwater worldwide. Several techniques are available to remove nitrate from water, but they are difficult to automate in remote settings or require chemicals for treatment for regeneration. Here, we demonstrate the use of two surfactant-treated high surface area porous electrodes for passive adsorption of nitrate followed by electrical regeneration. In order to generate the surface charge driving adsorption, we functionalized the active electrode (cathode) and capacitive counter electrode (anode) with cetrimonium bromide (CTAB) and sodium dodecyl benzene sulphonate (SDBS), respectively. We find voltage applied during regeneration is directly proportional to the subsequent available adsorption capacity at short circuit. In a recent preliminary work, we used a Faradaic counter electrode, and here, we compare both studies in terms of energy-normalized adsorbed salt (ENAS)—a measure of energy efficiency—and average salt adsorption rate (ASAR). We show that capacitive counter electrode used in this work increases ENAS by two orders of magnitude, while maintaining a similar ASAR.