CeO2/Bi2MoO6 heterostructured microspheres with synergistic effect for accelerating photogenerated charge separation

• Published in: Separation and purification technology 2019-03, Vol.211, p.474-480
• Main Authors: Yi, Junhui, Mo, Huimei, Zhang, Bangliang, Song, Jiaxing, Liu, Dongqin, Zhuo, Guanjie
• Format: Article
• Language: English
• Subjects: CeO2/Bi2MoO6; Heterostructured microspheres; Mechanism; Photocatalytic activity; Synergistic effect
• ISSN: 1383-5866; 1873-3794
• DOI: 10.1016/j.seppur.2018.10.022

[Display omitted] •CeO2/Bi2MoO6 heterostructured microspheres are successfully synthesized by precipitation and hydrothermal method.•Introduced CeO2 NPs significantly enhance the photoelectric photoactivity of Bi2MoO6 microspheres.•CeO2/Bi2MoO6 composite exhibit excellent stability for the photodegradation of AO-II.•The possible photocatalytic mechanism is discussed and proposed. CeO2/Bi2MoO6 heterostructured microspheres were successfully synthesized through precipitation and hydrothermal method. The as-obtained samples were well characterized by XRD, SEM, TEM, UV–Vis DRS and XPS. The photocatalytic activity was evaluated by degrading acid orange II (AO-II) under visible light irradiation. The test results show that CeO2/Bi2MoO6 heterostructured microspheres have broad absorption in the visible region and havemore superior catalytic activities than pure Bi2MoO6, which is attributed to the synergistic effect of the suitable band gap matching between CeO2 and Bi2MoO6. Moreover, 0.1CeO2/Bi2MoO6 composite has the highest activity. Radical scavenger experiments proves that the superoxide radical anions (O2−) and photogenerated holes (h+) are dominating active species. The recycling experiment confirms that CeO2/Bi2MoO6 heterostructure keep high stabilization during the photocatalytic reaction. Onthisbasis, a photogenerated charge carriers transfer and photocatalytic progress on the CeO2/Bi2MoO6 heterostructure has beendiscussed.