Microstructure and photoelectric properties of P-doped silicon-rich SiNx film as an n-type layer for PIN-type amorphous silicon thin film solar cells

•Nitrogen incorporation reduced the interface defect states of nanocrystalline silicon.•The conductivity of the prepared film was enhanced with proper nitrogen incorporation.•P-doped nc-SiNx:H may improve the performances of amorphous silicon thin film solar cells. In this study, the phosphorus dope...

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Bibliographic Details
Published in:Solar energy 2017-03, Vol.144, p.808-817
Main Authors: Ma, Deng-Hao, Zhang, Wei-Jia, Jiang, Zhao-Yi, Ma, Qiang, Ma, Xiao-Bo, Fan, Zhi-Qiang, Song, Deng-Yuan, Zhang, Lei
Format: Article
Language:English
Subjects:
Nitrogen incorporation
Phosphorus doping
Photoluminescence
Thin film solar cell
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Summary:•Nitrogen incorporation reduced the interface defect states of nanocrystalline silicon.•The conductivity of the prepared film was enhanced with proper nitrogen incorporation.•P-doped nc-SiNx:H may improve the performances of amorphous silicon thin film solar cells. In this study, the phosphorus doped silicon nanocrystals embedded in silicon-rich SiNx:H thin films were fabricated using a radio frequency plasma enhanced chemical vapor deposition technique, from a SiH4, pH3, H2 and NH3 mixture. The effects of nitrogen incorporation on the microstructure and photoelectric properties of the nc-Si:H film were systematically investigated. Raman and transmission electron microscope observation revealed the fact that nitrogen incorporation inhibited the growth of Si nanocrystals, and their sizes and densities of them could be adjusted by varying the incorporation flow ratio NH3/(SiH4+H2+pH3). The reduction of refractive index and improvement of conductivity of the prepared films were observed with increasing nitrogen impurity, and a maximal conductivity was obtained when the flow ratio was 0.02. In addition, the P-doped nc-SiNx:H film was used as an n-type layer for the amorphous silicon thin film solar cells to optimize its efficiency, and the solar cell with high fill factor (0.624) and efficiency (9.26%) has been obtained when the flow ratio was 0.02. As a result, the P-doped nc-SiNx:H film with proper nitrogen incorporation was able to efficiently improve the performance of the thin film solar cells.
ISSN:0038-092X
1471-1257
DOI:10.1016/j.solener.2017.02.019