Enhancing photovoltaic efficiency in flexible perovskite solar cells through the incorporation of up-conversion Er3+ doped forsterite thin films

• Published in: Solar energy materials and solar cells 2025-01, Vol.279, p.113251, Article 113251
• Main Authors: Alves, Annelise Kopp, Kaufmann Junior, Claudir Gabriel, Sun Zampiva, Rubia Young, Berutti, Felipe Amorim
• Format: Article
• Language: English
• Subjects: Erbium-doped forsterite; Near-infrared photon harvesting; Perovskite solar cells; Up-conversion materials
• ISSN: 0927-0248
• DOI: 10.1016/j.solmat.2024.113251

Perovskite solar cells (PSCs) have garnered attention due to their high efficiency and cost-effective production. However, their limited absorption in the near-infrared (NIR) range constrains their potential, as NIR accounts for 44 % of the solar spectrum. To address this, we incorporated an erbium-doped forsterite (Mg₂SiO₄:Er³⁺) up-conversion layer into flexible PSC (MAFA-CsPb(Br,I)₃), converting NIR photons into visible light to enhance power conversion efficiency (PCE). This integration resulted in a significant increase in PCE from 16.1 % to 20.6 %, with the device also showing improved open-circuit voltage (Voc) from 1.05 V to 1.19 V and a higher short-circuit current density (Jsc) from 22.1 to 23.1 mA/cm2. Additionally, the thermal and moisture stability of the cells was enhanced, retaining 75 % of their initial efficiency after 500 h under ambient conditions. The use of erbium-doped forsterite as an up-conversion layer presents a promising strategy for overcoming spectral limitations and improving the durability of PSCs, providing a pathway toward more efficient and stable next-generation photovoltaic devices. [Display omitted] •Novelty: Introduced erbium-doped forsterite (Mg2SiO4:Er3+) as a new up-conversion material to boost efficiency in flexible perovskite cells.•Efficiency Boost: Increased power conversion efficiency by 27%, from 16.1% to 20.6%, by converting IR to visible light.•Advanced Characterization:Used EBIC analysis to evaluate electrical contact quality between cell layers.•Stability Enhancement: Demonstrated superior thermal and moisture stability, retaining 75 % efficiency after 500 h of use.•DepositionTechnique: Used RF sputtering for uniform and controllable thin-film deposition, ensuring consistent up-conversion efficiency.