Experimental and theoretical analysis of the diffusion behavior of chromium(III) acetylacetonate in supercritical CO2

• Published in: The Journal of supercritical fluids 2016-12, Vol.118, p.153-162
• Main Authors: Cordeiro, Joana, Magalhães, Ana L., Valente, Anabela A., Silva, Carlos M.
• Format: Article
• Language: English
• Subjects: Chromatographic impulse response method; Chromium(III) acetylacetonate; Tracer diffusion coefficient measurement
• ISSN: 0896-8446; 1872-8162
• DOI: 10.1016/j.supflu.2016.08.006

[Display omitted] ⿢Tracer diffusivities (D12) in supercritical mixtures are fundamental for research and design.⿢Measurement of tracer diffusivities of chromium(III) acetylacetonate in SC-CO2.⿢Chromatographic Impulse Response method applied over 308.15⿿333.15K and 125⿿250bar.⿢Range of D12 data of (5.700⿿1.529)ÿ10⿿4cm2s⿿1, and analysis of experimental trends obtained.⿢Accurate modeling performed with hydrodynamic, free-volume and semi-empirical equations. The tracer diffusion coefficients, D12, of solutes in supercritical carbon dioxide (SC-CO2), modified or not with cosolvents, are necessary for industrial and research applications. In this study, the determination and analysis of D12 values of chromium(III) acetylacetonate in SC-CO2 are presented. The measurements were carried out by the chromatographic impulse response (CIR) method from 308.15 to 333.15K at pressures from 125 to 250bar, and yield diffusivities between 0.570ÿ10⿿4 and 1.529ÿ10⿿4cm2⿿s⿿1 The experimental trends of D12 with temperature, pressure, density, and Stokes-Einstein coordinates are also presented. Eleven equations were evaluated for modeling the new data, and the best results were achieved using the semi-empirical correlations of Magalhães et al. (error of 1.95% and 1.90%), the universal model of Lito et al. (2.01%), and the predictive modified Stokes⿿Einstein equation (3.16%) and Vaz et al. expression (3.27%). Finally, a comparison between the diffusivities of this work and those reported in the literature for other metal acetylacetonates (Co(acac)3, Cr(acac)3, Pd(acac)2 and Pt(acac)2) was accomplished, being possible to conclude that the correct interpretation of the diffusive phenomenon of these systems requires not only the molecular weight but also solute diameter.