Supercritical water depolymerization of black liquor, refining and comprehensive analysis of products including biopolyols

• Published in: The Journal of supercritical fluids 2024-09, Vol.211, p.106296, Article 106296
• Main Authors: Demirkaya, Emre, Cocero, María José, Cantero, Danilo
• Format: Article
• Language: English
• Subjects: Biorefinery; Fractionation; Hydrothermal; Polyol; SAF
• ISSN: 0896-8446; 1872-8162
• DOI: 10.1016/j.supflu.2024.106296

Black liquor (BL) has valuable lignin and its derived compounds, which can be used for many purposes, such as polyol synthesis. Herein, we reveal polyols presence in depolymerized black liquor (DBL) and propose a fast and scalable approach to increase the yield of this fraction. Hydrothermal treatment (HTL) of black liquor (385°C, 26 MPa) was performed in a custom designed supercritical water (SCW) pilot-plant with rapid reaction times of around 0.4 s. Ash-free, total ethyl acetate extracted bio-oil yield was found 77% w/w. In addition to the contribution of the detailed fractionation methods, this study highlights continuous operation (>1 hour), and short reaction times (∼0.4 s) of raw black liquor in SCW to produce biopolyols and aromatic bio-oil. [Display omitted] •Black liquor depolymerization in SCW produces biopolyols.•Hydrothermal treatment provided 77% w/w bio-oil yield in 0.4 sec.•Monomer yield found 30% w/w more in the depolymerized black liquor compared to raw black liquor.•Inorganics could be reused in pulping process by integrating to its process cycle.•Aromatic monomers; guaiacol and syringol were produced during the process.