Plasma electrolytic oxidation coatings on AZ31 magnesium alloys with Si3N4 nanoparticle additives

• Published in: Surface & coatings technology 2017-12, Vol.332, p.358-367
• Main Authors: Lou, Bih-Show, Lin, Yi-Yuan, Tseng, Chuan-Ming, Lu, Yu-Chu, Duh, Jenq-Gong, Lee, Jyh-Wei
• Format: Article
• Language: English
• Subjects: Adhesion; AZ31 alloy; Corrosion resistance; Pin-on-disk wear; Plasma electrolytic oxidation; Si3N4 nanoparticle
• ISSN: 0257-8972; 1879-3347
• DOI: 10.1016/j.surfcoat.2017.05.094

Magnesium AZ31 alloys have been widely used in the aerospace, automotive, and personal computer industries due to their light weight and low density. However, high chemical reactivity, poor corrosion and wear resistance limit their further use in many other fields. The plasma electrolytic oxidation (PEO) process can produce a protective oxide layer on the Mg alloy to improve its mechanical property, wear resistance, and corrosion resistance. In this work, silicon nitride (Si3N4) nanoparticles were added into the reaction electrolyte to study their influence on the microstructure, mechanical, and anticorrosion properties of PEO coatings on AZ31 Mg alloy. The breakdown voltage for igniting the plasma discharge decreased with increasing concentration of Si3N4 nanoparticles. The PEO coating without Si3N4 additives in the reaction electrolyte had mainly MgAl2O4 and minor MgO phases. On the other hand, when Si3N4 nanoparticles were included in the PEO reaction, a Mg2SiO4 phase is present. In general, the coating thickness, surface roughness, hardness and elastic modulus increased with increasing Si3N4 nanoparticle concentration up to 3g/L. A maximum hardness of 16.4GPa was found in the coating fabricated with 3g/L Si3N4 nanoparticles added. The PEO coating fabricated using 2g/L of Si3N4 nanoparticles in its electrolyte exhibited the best corrosion resistance, high hardness, good adhesion, and low coefficient of friction in this study. •The MgAl2O4 based oxide layer is grown on AZ31 Mg alloy by plasma electrolytic oxidation (PEO) process.•The added Si3N4 nanoparticles in electrolyte greatly enhance the hardness of PEO grown oxide to 16.3GPa.•The oxide coating exhibits high hardness, improved anti-corrosion, adhesion and wear resistance with 2g/L Si3N4 additive.